NCERT Exemplar Problem Solutions 12 Chemistry

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NCERT Exemplar Problems Class 12 Chemistry

NCERT Solutions Class 12 Chemistry

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Chapter 1: Solid State

Chapter 2: Solutions

Chapter 3: Electrochemistry

Chapter 4: Chemical Kinetics

Chapter 5: Surface Chemistry

Chapter 6: General Principles and Processes of Isolation of Elements

Chapter 7: The p – Block Elements

Chapter 8: The d – and f – Block Elements

Chapter 9: Coordinate Compounds

Chapter 10: Haloalkanes and Haloarenes

Chapter 11: Alcohols, Phenols and Ethers

Chapter 12: Aldehydes, Ketones and Carboxylic Acids

Chapter 13: Amines

Chapter 14: Biomolecules

Chapter 15: Polymers

Chapter 16: Chemistry in Everyday Life


Points to Remember

Chapter 1: Solid State
Classification of solids based on different binding forces: molecular, ionic, covalent and metallic solids, amorphous and crystalline solids (elementary idea). Unit cell in two dimensional and three dimensional lattices, calculation of density of unit cell, packing in solids, packing efficiency, voids, number of atoms per unit cell in a cubic unit cell, point defects, electrical and magnetic properties. Band theory of metals, conductors, semiconductors and insulators and n and p type semiconductors.

Chapter 2: Solutions
Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases in liquids, solid solutions, colligative properties – relative lowering of vapour pressure, Raoult’s law, elevation of boiling point, depression of freezing point, osmotic pressure, determination of molecular masses using colligative properties, abnormal molecular mass, Van’t Hoff factor.

Chapter 3: Electrochemistry
Redox reactions, conductance in electrolytic solutions, specific and molar conductivity, variations of conductivity with concentration, Kohlrausch’s Law, electrolysis and law of electrolysis (elementary idea), dry cell-electrolytic cells and Galvanic cells, lead accumulator, EMF of a cell, standard electrode potential, Nernst equation and its application to chemical cells, Relation between Gibbs energy change and EMF of a cell, fuel cells, corrosion.

Chapter 4: Chemical Kinetics
Rate of a reaction (Average and instantaneous), factors affecting rate of reaction: concentration, temperature, catalyst; order and molecularity of a reaction, rate law and specific rate constant,integrated rate equations and half life (only for zero and first order reactions), concept of collision theory (elementary idea, no mathematical treatment). Activation energy, Arrhenious equation.

Chapter 5: Surface Chemistry
Adsorption – physisorption and chemisorption, factors affecting adsorption of gases on solids, catalysis, homogenous and heterogenous activity and selectivity; enzyme catalysis colloidal state distinction between true solutions, colloids and suspension; lyophilic, lyophobic multi-molecular and macromolecular colloids; properties of colloids; Tyndall effect, Brownian movement, electrophoresis, coagulation, emulsion – types of emulsions.

Chapter 6: General Principles and Processes of Isolation of Elements
Principles and methods of extraction – concentration, oxidation, reduction – electrolytic method and refining; occurrence and principles of extraction of aluminium, copper, zinc and iron.

Chapter 7: “p”-Block Elements
Group -15 Elements: General introduction, electronic configuration, occurrence, oxidation states, trends in physical and chemical properties; Nitrogen preparation properties and uses; compounds of Nitrogen, preparation and properties of Ammonia and Nitric Acid, Oxides of Nitrogen(Structure only) ; Phosphorus – allotropic forms, compounds of Phosphorus: Preparation and Properties of Phosphine, Halides and Oxoacids (elementary idea only). Group 16 Elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties, dioxygen: Preparation, Properties and uses, classification of Oxides, Ozone, Sulphur -allotropic forms; compounds of Sulphur: Preparation Properties and uses of Sulphur-dioxide, Sulphuric Acid: industrial process of manufacture, properties and uses; Oxoacids of Sulphur (Structures only). Group 17 Elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties; compounds of halogens, Preparation, properties and uses of Chlorine and Hydrochloric acid, interhalogen compounds, Oxoacids of halogens (structures only). Group 18 Elements: General introduction, electronic configuration, occurrence, trends in physical and chemical properties, uses.

Chapter 8: “d” and “f” Block Elements
General introduction, electronic configuration, occurrence and characteristics of transition metals, general trends in properties of the first row transition metals – metallic character, ionization enthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitial compounds, alloy formation, preparation and properties of K2Cr2O7 and KMnO4. Lanthanoids – Electronic configuration, oxidation states, chemical reactivity and lanthanoid contraction and its consequences. Actinoids – Electronic configuration, oxidation states and comparison with lanthanoids.

Chapter 9: Coordination Compounds
Coordination compounds – Introduction, ligands, coordination number, colour, magnetic properties and shapes, IUPAC nomenclature of mononuclear coordination compounds. Bonding, Werner’s theory, VBT, and CFT; structure and stereoisomerism, importance of coordination compounds (in qualitative inclusion, extraction of metals and biological system).

Chapter 10: Haloalkanes and Haloarenes.
Haloalkanes: Nomenclature, nature of C–X bond, physical and chemical properties, mechanism of substitution reactions, optical rotation. Haloarenes: Nature of C–X bond, substitution reactions (Directive influence of halogen in monosubstituted compounds only). Uses and environmental effects of – dichloromethane, trichloromethane, tetrachloromethane, iodoform, freons, DDT.

Chapter 11: Alcohols, Phenols and Ethers
Alcohols: Nomenclature, methods of preparation, physical and chemical properties (of primary alcohols only), identification of primary, secondary and tertiary alcohols, mechanism of dehydration, uses with special reference to methanol and ethanol. Phenols: Nomenclature, methods of preparation, physical and chemical properties, acidic nature of phenol, electrophillic substitution reactions, uses of phenols. Ethers: Nomenclature, methods of preparation, physical and chemical properties, uses.

Chapter 12: Aldehydes, Ketones and Carboxylic Acids
Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation, physical and chemical properties, mechanism of nucleophilic addition, reactivity of alpha hydrogen in aldehydes: uses. Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemical properties; uses.

Chapter 13: Organic compounds containing Nitrogen
Amines: Nomenclature, classification, structure, methods of preparation, physical and chemical properties, uses, identification of primary, secondary and tertiary amines. Cyanides and Isocyanides – will be mentioned at relevant places in text. Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry.
Chapter 14: Biomolecules
Carbohydrates – Classification (aldoses and ketoses), monosaccahrides (glucose and fructose), D-L configuration oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose, glycogen); Importance of carbohydrates. Proteins -Elementary idea of – amino acids, peptide bond, polypeptides, proteins, structure of proteins – primary, secondary, tertiary structure and quaternary structures (qualitative idea only), denaturation of proteins; enzymes. Hormones – Elementary idea excluding structure.  Vitamins – Classification and functions.
Nucleic Acids: DNA and RNA.

Chapter 15: Polymers
Classification – natural and synthetic, methods of polymerization (addition and condensation), copolymerization, some important polymers: natural and synthetic like polythene, nylon polyesters, bakelite, rubber. Biodegradable and non-biodegradable polymers.

Chapter 16: Chemistry in Everyday life
Chemicals in medicines – analgesics, tranquilizers antiseptics, disinfectants, antimicrobials, antifertility drugs, antibiotics, antacids, antihistamines. Chemicals in food – preservatives, artificial sweetening agents, elementary idea of antioxidants. Cleansing agents- soaps and detergents, cleansing action.